https://en.wikipedia.org/w/index.php?action=history&feed=atom&title=Talk%3AAstatine Talk:Astatine - Revision history 2024-10-17T08:25:10Z Revision history for this page on the wiki MediaWiki 1.43.0-wmf.26 https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1198414344&oldid=prev Sandbh: /* Density of fcc metallic At (conjectures) */ 2024-01-24T02:10:18Z <p><span class="autocomment">Density of fcc metallic At (conjectures)</span></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 02:10, 24 January 2024</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 85:</td> <td colspan="2" class="diff-lineno">Line 85:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>metallic solids as a consequence of an emerging polarization catastrophe. As these polarizabilities increase monotonically proceeding down the halogen group, the estimated compressions necessary for metallization decrease monotonically" ({{doi|10.1103/PhysRevLett.111.116404}}, p. 2). The polarizability for I is 32.9± atomic units and that for At is 42.2±4. On this basis the density of At is 42.2/32.9 x 7.83 (fcc I density) = 10.04 gm/cc. --- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 06:32, 13 January 2024 (UTC)</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>metallic solids as a consequence of an emerging polarization catastrophe. As these polarizabilities increase monotonically proceeding down the halogen group, the estimated compressions necessary for metallization decrease monotonically" ({{doi|10.1103/PhysRevLett.111.116404}}, p. 2). The polarizability for I is 32.9± atomic units and that for At is 42.2±4. On this basis the density of At is 42.2/32.9 x 7.83 (fcc I density) = 10.04 gm/cc. --- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 06:32, 13 January 2024 (UTC)</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:At high pressure, wouldn't the interatomic distance be smaller because of volume compression? So I guess hypothetical fcc iodine density at standard pressure (if that state could persist) would be somewhat lower than 7.83 (not sure how much). But these are conjectural anyway. [[User:Double sharp|Double sharp]] ([[User talk:Double sharp|talk]]) 07:43, 14 January 2024 (UTC)</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:At high pressure, wouldn't the interatomic distance be smaller because of volume compression? So I guess hypothetical fcc iodine density at standard pressure (if that state could persist) would be somewhat lower than 7.83 (not sure how much). But these are conjectural anyway. [[User:Double sharp|Double sharp]] ([[User talk:Double sharp|talk]]) 07:43, 14 January 2024 (UTC)</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>From Arblaster (2018 p. 604):</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>:"Hermann et al. 2013 have indicated that the correct room temperature structure is the metallic form and is probably face-centered cubic (cF4) with an estimated lattice parameter of 0.539 nm (Hermann 2014) which leads to the estimated crytallographic properties given in Table 85. The molar volume is notably lower than the range of 33.9 to 34.5 cm&lt;sup&gt;2&lt;/sup&gt; mol&lt;sup&gt;–1&lt;/sup&gt; estimated by Bonchev and Kamenska 1981 using the technique of information indices."</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>They give a density of 8.91 gm/cc for At-210, and 8.95 for At-211. The molar volume is 23.6 cc/mol. --- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 02:09, 24 January 2024 (UTC)</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>* Arblaster JW (ed.) 2018, ''Selected Values of the Crystallographic Properties of Elements,'' ASM International, Materials Park, Ohio</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>* Hermann A 2014, Priv.Comm., 10 January</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>--- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 02:09, 24 January 2024 (UTC)</div></td> </tr> </table> Sandbh https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1195572033&oldid=prev Sandbh: /* Density of fcc metallic At (conjectures) */ 2024-01-14T11:34:05Z <p><span class="autocomment">Density of fcc metallic At (conjectures)</span></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 11:34, 14 January 2024</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 72:</td> <td colspan="2" class="diff-lineno">Line 72:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Density of fcc metallic At (conjectures) ==</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Density of fcc metallic At (conjectures) ==</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>'''1.''' Iodine at 53 GPa adopts a <del style="font-weight: bold; text-decoration: none;">metaliic</del> FCC structure, with a volume (Å/atom) of 19.91 ({{doi|10.1103/physrevb.49.3725}}, p. 3727). Such a stucture has a packing efficiency of 74%.</div></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>'''1.''' Iodine at 53 GPa adopts a <ins style="font-weight: bold; text-decoration: none;">metallic</ins> FCC structure, with a volume (Å/atom) of 19.91 ({{doi|10.1103/physrevb.49.3725}}, p. 3727). Such a stucture has a packing efficiency of 74%.</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>The volume of one mole of such iodine atoms is 19.91 x 10&lt;sup&gt;–24&lt;/sup&gt; x 6.022 x 10&lt;sup&gt;23&lt;/sup&gt; = 11.99 cc.</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>The volume of one mole of such iodine atoms is 19.91 x 10&lt;sup&gt;–24&lt;/sup&gt; x 6.022 x 10&lt;sup&gt;23&lt;/sup&gt; = 11.99 cc.</div></td> </tr> </table> Sandbh https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1195572003&oldid=prev Sandbh: /* Density of fcc metallic At (conjectures) */ 2024-01-14T11:33:43Z <p><span class="autocomment">Density of fcc metallic At (conjectures)</span></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 11:33, 14 January 2024</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 72:</td> <td colspan="2" class="diff-lineno">Line 72:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Density of fcc metallic At (conjectures) ==</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Density of fcc metallic At (conjectures) ==</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>'''1.''' Iodine at 53 GPa adopts a <del style="font-weight: bold; text-decoration: none;">metalic</del> FCC structure, with a volume (Å/atom) of 19.91 ({{doi|10.1103/physrevb.49.3725}}, p. 3727). Such a stucture has a packing efficiency of 74%.</div></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>'''1.''' Iodine at 53 GPa adopts a <ins style="font-weight: bold; text-decoration: none;">metaliic</ins> FCC structure, with a volume (Å/atom) of 19.91 ({{doi|10.1103/physrevb.49.3725}}, p. 3727). Such a stucture has a packing efficiency of 74%.</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>The volume of one mole of such iodine atoms is 19.91 x 10&lt;sup&gt;–24&lt;/sup&gt; x 6.022 x 10&lt;sup&gt;23&lt;/sup&gt; = 11.99 cc.</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>The volume of one mole of such iodine atoms is 19.91 x 10&lt;sup&gt;–24&lt;/sup&gt; x 6.022 x 10&lt;sup&gt;23&lt;/sup&gt; = 11.99 cc.</div></td> </tr> </table> Sandbh https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1195540383&oldid=prev Double sharp: /* Density of fcc metallic At (conjectures) */ 2024-01-14T07:43:53Z <p><span class="autocomment">Density of fcc metallic At (conjectures)</span></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 07:43, 14 January 2024</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 84:</td> <td colspan="2" class="diff-lineno">Line 84:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>'''3.''' "From the known atomic or molecular dipole polarizabilities, we can estimate the atomic densities required to form</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>'''3.''' "From the known atomic or molecular dipole polarizabilities, we can estimate the atomic densities required to form</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>metallic solids as a consequence of an emerging polarization catastrophe. As these polarizabilities increase monotonically proceeding down the halogen group, the estimated compressions necessary for metallization decrease monotonically" ({{doi|10.1103/PhysRevLett.111.116404}}, p. 2). The polarizability for I is 32.9± atomic units and that for At is 42.2±4. On this basis the density of At is 42.2/32.9 x 7.83 (fcc I density) = 10.04 gm/cc. --- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 06:32, 13 January 2024 (UTC)</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>metallic solids as a consequence of an emerging polarization catastrophe. As these polarizabilities increase monotonically proceeding down the halogen group, the estimated compressions necessary for metallization decrease monotonically" ({{doi|10.1103/PhysRevLett.111.116404}}, p. 2). The polarizability for I is 32.9± atomic units and that for At is 42.2±4. On this basis the density of At is 42.2/32.9 x 7.83 (fcc I density) = 10.04 gm/cc. --- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 06:32, 13 January 2024 (UTC)</div></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>:At high pressure, wouldn't the interatomic distance be smaller because of volume compression? So I guess hypothetical fcc <del style="font-weight: bold; text-decoration: none;">I</del> density at standard pressure (if that state could persist) would be somewhat lower than 7.83 (not sure how much). But these are conjectural anyway. [[User:Double sharp|Double sharp]] ([[User talk:Double sharp|talk]]) 07:43, 14 January 2024 (UTC)</div></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>:At high pressure, wouldn't the interatomic distance be smaller because of volume compression? So I guess hypothetical fcc <ins style="font-weight: bold; text-decoration: none;">iodine</ins> density at standard pressure (if that state could persist) would be somewhat lower than 7.83 (not sure how much). But these are conjectural anyway. [[User:Double sharp|Double sharp]] ([[User talk:Double sharp|talk]]) 07:43, 14 January 2024 (UTC)</div></td> </tr> </table> Double sharp https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1195540298&oldid=prev Double sharp: /* Density of fcc metallic At (conjectures) */ 2024-01-14T07:43:14Z <p><span class="autocomment">Density of fcc metallic At (conjectures)</span></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 07:43, 14 January 2024</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 84:</td> <td colspan="2" class="diff-lineno">Line 84:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>'''3.''' "From the known atomic or molecular dipole polarizabilities, we can estimate the atomic densities required to form</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>'''3.''' "From the known atomic or molecular dipole polarizabilities, we can estimate the atomic densities required to form</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>metallic solids as a consequence of an emerging polarization catastrophe. As these polarizabilities increase monotonically proceeding down the halogen group, the estimated compressions necessary for metallization decrease monotonically" ({{doi|10.1103/PhysRevLett.111.116404}}, p. 2). The polarizability for I is 32.9± atomic units and that for At is 42.2±4. On this basis the density of At is 42.2/32.9 x 7.83 (fcc I density) = 10.04 gm/cc. --- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 06:32, 13 January 2024 (UTC)</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>metallic solids as a consequence of an emerging polarization catastrophe. As these polarizabilities increase monotonically proceeding down the halogen group, the estimated compressions necessary for metallization decrease monotonically" ({{doi|10.1103/PhysRevLett.111.116404}}, p. 2). The polarizability for I is 32.9± atomic units and that for At is 42.2±4. On this basis the density of At is 42.2/32.9 x 7.83 (fcc I density) = 10.04 gm/cc. --- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 06:32, 13 January 2024 (UTC)</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>:At high pressure, wouldn't the interatomic distance be smaller because of volume compression? So I guess hypothetical fcc I density at standard pressure (if that state could persist) would be somewhat lower than 7.83 (not sure how much). But these are conjectural anyway. [[User:Double sharp|Double sharp]] ([[User talk:Double sharp|talk]]) 07:43, 14 January 2024 (UTC)</div></td> </tr> </table> Double sharp https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1195290447&oldid=prev Sandbh: /* Density of fcc metallic At (conjectures) */ new section 2024-01-13T06:32:19Z <p><span class="autocomment">Density of fcc metallic At (conjectures): </span> new section</p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 06:32, 13 January 2024</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 69:</td> <td colspan="2" class="diff-lineno">Line 69:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:There are no experimentally determined values for them. Various predicted values have been published, but there are too many to list exhaustively and there's no reason to favor one source over another; thus they are not included in the article &lt;sup&gt;[[User:ComplexRational|'''&lt;span style="color:#0039a6"&gt;Complex&lt;/span&gt;''']]&lt;/sup&gt;/&lt;sub&gt;[[User talk:ComplexRational|'''&lt;span style="color:#000000"&gt;Rational&lt;/span&gt;''']]&lt;/sub&gt; 20:03, 7 October 2023 (UTC)</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:There are no experimentally determined values for them. Various predicted values have been published, but there are too many to list exhaustively and there's no reason to favor one source over another; thus they are not included in the article &lt;sup&gt;[[User:ComplexRational|'''&lt;span style="color:#0039a6"&gt;Complex&lt;/span&gt;''']]&lt;/sup&gt;/&lt;sub&gt;[[User talk:ComplexRational|'''&lt;span style="color:#000000"&gt;Rational&lt;/span&gt;''']]&lt;/sub&gt; 20:03, 7 October 2023 (UTC)</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>::The other thing is that most of the values in the literature are predictions for At&lt;sub&gt;2&lt;/sub&gt;, and we don't know if condensed astatine is actually going to be diatomic. [[User:Double sharp|Double sharp]] ([[User talk:Double sharp|talk]]) 08:44, 11 October 2023 (UTC)</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>::The other thing is that most of the values in the literature are predictions for At&lt;sub&gt;2&lt;/sub&gt;, and we don't know if condensed astatine is actually going to be diatomic. [[User:Double sharp|Double sharp]] ([[User talk:Double sharp|talk]]) 08:44, 11 October 2023 (UTC)</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>== Density of fcc metallic At (conjectures) ==</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>'''1.''' Iodine at 53 GPa adopts a metalic FCC structure, with a volume (Å/atom) of 19.91 ({{doi|10.1103/physrevb.49.3725}}, p. 3727). Such a stucture has a packing efficiency of 74%.</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>The volume of one mole of such iodine atoms is 19.91 x 10&lt;sup&gt;–24&lt;/sup&gt; x 6.022 x 10&lt;sup&gt;23&lt;/sup&gt; = 11.99 cc.</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>Since the atomic weight of iodine is 126.9 this suggests a density of 0.74 x 126.9/11.99 = 7.83 gm/cc, compared to 4.93 gm/cc for ordinary iodine. Thus, the density from orthorhombic to fcc iodine increases 1.58 times.</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>If this occurs for fcc astatine, it suggests a density of 6.2–6.5 x 1.58 = 10.03±0.24 gm/cc. The figure of 6.2–6.5 is from {{doi|10.1021/j150609a021|10.1021/j150609a021}}, pp. 1182, 1185).</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>'''2.''' Another way to look at this is the metallization collapse that occurs when R/V = 1. Here, R = molar refractivity and V = molar volume. Pauling pointed out that the cube root of molar refractivity is tantamount to an approximate measure of the radius of the outermost valence electrons in the atom. [https://www.knowledgedoor.com/2/elements_handbook/orbital_radius.html The orbital radius of At] is 114.6 pm. Cubed, this yields an R value value of 15.05 cc which is ≈ to V. The density is then the atomic weight of At = 210 divided by the molar volume of 11.137 cc = 13.96 x 0.74 packing efficiency = 10.33 gm/cc.</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>'''3.''' "From the known atomic or molecular dipole polarizabilities, we can estimate the atomic densities required to form</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>metallic solids as a consequence of an emerging polarization catastrophe. As these polarizabilities increase monotonically proceeding down the halogen group, the estimated compressions necessary for metallization decrease monotonically" ({{doi|10.1103/PhysRevLett.111.116404}}, p. 2). The polarizability for I is 32.9± atomic units and that for At is 42.2±4. On this basis the density of At is 42.2/32.9 x 7.83 (fcc I density) = 10.04 gm/cc. --- [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 06:32, 13 January 2024 (UTC)</div></td> </tr> </table> Sandbh https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1192312341&oldid=prev Praseodymium-141: Assessment: banner shell, Elements, Guild of Copy Editors, −Vital article (Rater) 2023-12-28T18:44:27Z <p>Assessment: banner shell, Elements, Guild of Copy Editors, −Vital article (<a href="/wiki/Wikipedia:RATER#2.7.0" class="mw-redirect" title="Wikipedia:RATER">Rater</a>)</p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 18:44, 28 December 2023</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 25:</td> <td colspan="2" class="diff-lineno">Line 25:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|maindate2=16 September 2023</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|maindate2=16 September 2023</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>}}</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>}}</div></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>{{WikiProject banner shell|collapsed=yes|1=</div></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>{{WikiProject banner shell<ins style="font-weight: bold; text-decoration: none;">|class=FA</ins>|collapsed<ins style="font-weight: bold; text-decoration: none;">=yes|vital</ins>=yes|1=</div></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>{{WikiProject Elements|<del style="font-weight: bold; text-decoration: none;">class</del> = <del style="font-weight: bold; text-decoration: none;">FA|importance=</del>Mid}}</div></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>{{WikiProject Elements|<ins style="font-weight: bold; text-decoration: none;">importance</ins> = Mid}}</div></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>{{<del style="font-weight: bold; text-decoration: none;">GOCE</del>|user=Allens|date=17 February 2012 – 21 May 2012}}</div></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>{{<ins style="font-weight: bold; text-decoration: none;">WikiProject Guild of Copy Editors</ins>|user=Allens|date=17 February 2012 – 21 May 2012}}</div></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>{{Vital article|level=4|topic=Science|class = FA|subpage=Physics}}</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>}}</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>}}</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>{{User:MiszaBot/config</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>{{User:MiszaBot/config</div></td> </tr> </table> Praseodymium-141 https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1182955170&oldid=prev PrimeBOT: /* top */Task 24: banner removal following a TFD 2023-11-01T11:54:49Z <p><span class="autocomment">top: </span><a href="/wiki/User:PrimeBOT/24" class="mw-redirect" title="User:PrimeBOT/24">Task 24</a>: banner removal following <a href="/wiki/Wikipedia:Templates_for_discussion/Log/2023_October_9" title="Wikipedia:Templates for discussion/Log/2023 October 9">a TFD</a></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 11:54, 1 November 2023</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 28:</td> <td colspan="2" class="diff-lineno">Line 28:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>{{WikiProject Elements|class = FA|importance=Mid}}</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>{{WikiProject Elements|class = FA|importance=Mid}}</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>{{GOCE|user=Allens|date=17 February 2012 – 21 May 2012}}</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>{{GOCE|user=Allens|date=17 February 2012 – 21 May 2012}}</div></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>{{WP1.0 |class=FA |WPCD=yes |importance=Low}}</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>{{Vital article|level=4|topic=Science|class = FA|subpage=Physics}}</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>{{Vital article|level=4|topic=Science|class = FA|subpage=Physics}}</div></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>}}</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>}}</div></td> </tr> </table> PrimeBOT https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1179614903&oldid=prev Double sharp: /* Melting and boiling points */ 2023-10-11T08:44:36Z <p><span class="autocomment">Melting and boiling points</span></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 08:44, 11 October 2023</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 70:</td> <td colspan="2" class="diff-lineno">Line 70:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:There are no experimentally determined values for them. Various predicted values have been published, but there are too many to list exhaustively and there's no reason to favor one source over another; thus they are not included in the article &lt;sup&gt;[[User:ComplexRational|'''&lt;span style="color:#0039a6"&gt;Complex&lt;/span&gt;''']]&lt;/sup&gt;/&lt;sub&gt;[[User talk:ComplexRational|'''&lt;span style="color:#000000"&gt;Rational&lt;/span&gt;''']]&lt;/sub&gt; 20:03, 7 October 2023 (UTC)</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:There are no experimentally determined values for them. Various predicted values have been published, but there are too many to list exhaustively and there's no reason to favor one source over another; thus they are not included in the article &lt;sup&gt;[[User:ComplexRational|'''&lt;span style="color:#0039a6"&gt;Complex&lt;/span&gt;''']]&lt;/sup&gt;/&lt;sub&gt;[[User talk:ComplexRational|'''&lt;span style="color:#000000"&gt;Rational&lt;/span&gt;''']]&lt;/sub&gt; 20:03, 7 October 2023 (UTC)</div></td> </tr> <tr> <td colspan="2" class="diff-empty diff-side-deleted"></td> <td class="diff-marker" data-marker="+"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>::The other thing is that most of the values in the literature are predictions for At&lt;sub&gt;2&lt;/sub&gt;, and we don't know if condensed astatine is actually going to be diatomic. [[User:Double sharp|Double sharp]] ([[User talk:Double sharp|talk]]) 08:44, 11 October 2023 (UTC)</div></td> </tr> </table> Double sharp https://en.wikipedia.org/w/index.php?title=Talk:Astatine&diff=1179115531&oldid=prev Lowercase sigmabot III: Archiving 2 discussion(s) to Talk:Astatine/Archive 2) (bot 2023-10-08T00:22:14Z <p>Archiving 2 discussion(s) to <a href="/wiki/Talk:Astatine/Archive_2" title="Talk:Astatine/Archive 2">Talk:Astatine/Archive 2</a>) (bot</p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Previous revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 00:22, 8 October 2023</td> </tr><tr> <td colspan="2" class="diff-lineno">Line 44:</td> <td colspan="2" class="diff-lineno">Line 44:</td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>When solid, Cl, Br and I have orthorhombic crystalline structures. The volumes of the respective unit cells are 230.91, 262.1046 and 341.5684 cubic Å. The crystalline atomic radii are 0.99, 1.135 and 1.345 Å. If astatine instead has an (unmetallic) orthorhombic structure, its unit cell volume can be indicatively extrapolated using the cube of its predicted covalent atomic radius of 1.5 Å. Its crystalline atomic radius may be marginally larger due to intralayer bonding, as appears to occur in iodine, but I’ll ignore this possibility as I have no way of quantifying it. A straight line extrapolation (R-squared = 0.9989) of unit cell volume for Cl, Br, and I vs. the cube of atomic radius for Cl, Br, I and At indicates an atomic volume for At of 412.3276. There are eight atoms in an orthorhombic unit cell so that gives a density (from the above calcs for metallic astatine) of 278.96 x 10^(–23) grams/412.3276 cubic Å = 6.76 grams per cubic centimetre, noting it is likely to be less than this given stronger intralayer bonding. For comparison, the figure cited in the article is 6.35 ±0.15. [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 03:16, 17 April 2015‎ (UTC)</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>When solid, Cl, Br and I have orthorhombic crystalline structures. The volumes of the respective unit cells are 230.91, 262.1046 and 341.5684 cubic Å. The crystalline atomic radii are 0.99, 1.135 and 1.345 Å. If astatine instead has an (unmetallic) orthorhombic structure, its unit cell volume can be indicatively extrapolated using the cube of its predicted covalent atomic radius of 1.5 Å. Its crystalline atomic radius may be marginally larger due to intralayer bonding, as appears to occur in iodine, but I’ll ignore this possibility as I have no way of quantifying it. A straight line extrapolation (R-squared = 0.9989) of unit cell volume for Cl, Br, and I vs. the cube of atomic radius for Cl, Br, I and At indicates an atomic volume for At of 412.3276. There are eight atoms in an orthorhombic unit cell so that gives a density (from the above calcs for metallic astatine) of 278.96 x 10^(–23) grams/412.3276 cubic Å = 6.76 grams per cubic centimetre, noting it is likely to be less than this given stronger intralayer bonding. For comparison, the figure cited in the article is 6.35 ±0.15. [[User:Sandbh|Sandbh]] ([[User talk:Sandbh|talk]]) 03:16, 17 April 2015‎ (UTC)</div></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><br /></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>== "Astitene" listed at [[Wikipedia:Redirects for discussion|Redirects for discussion]] ==</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>[[File:Information.svg|30px]]</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>A discussion is taking place to address the redirect [[:Astitene]]. The discussion will occur at [[Wikipedia:Redirects for discussion/Log/2021 April 21#Astitene]] until a consensus is reached, and readers of this page are welcome to contribute to the discussion. &lt;!-- from Template:RFDNote --&gt; –[[User:LaundryPizza03|&lt;b style="color:#77b"&gt;Laundry&lt;/b&gt;&lt;b style="color:#fb0"&gt;Pizza&lt;/b&gt;&lt;b style="color:#b00"&gt;03&lt;/b&gt;]] ([[User talk:LaundryPizza03|&lt;span style="color:#0d0"&gt;d&lt;/span&gt;]][[Special:Contribs/LaundryPizza03|&lt;span style="color:#0bf"&gt;c̄&lt;/span&gt;]]) 17:50, 21 April 2021 (UTC)</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><br /></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>== Bombarding? ==</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><br /></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Is "bombarding" really a scientific term that can be used at the end of the article, right at the end of the lead, before the subsections? [[User:FikaMedHasse|FikaMedHasse]] ([[User talk:FikaMedHasse|talk]]) 10:53, 11 November 2021 (UTC)</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>:It's the standard term in this context, yes. [[User:DMacks|DMacks]] ([[User talk:DMacks|talk]]) 11:29, 11 November 2021 (UTC)</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><br /></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Okay, thank you. I just found the phrase a bit comical. [[User:FikaMedHasse|FikaMedHasse]] ([[User talk:FikaMedHasse|talk]]) 11:37, 12 November 2021 (UTC)</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker" data-marker="−"></td> <td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>:Sometimes science adopts lay-language words and uses interesting shades of meaning or things that sound funny. In this case, an early ref is [[Enrico Fermi]]'s "Artificial Radioactivity produced by Neutron Bombardment" article from 1934 ([[doi:10.1098/rspa.1934.0168]]). [[List of unusual units of measurement]] is a good read. [[User:DMacks|DMacks]] ([[User talk:DMacks|talk]]) 16:34, 12 November 2021 (UTC)</div></td> <td colspan="2" class="diff-empty diff-side-added"></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br /></td> </tr> <tr> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== More recent papers on At chemistry ==</div></td> <td class="diff-marker"></td> <td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== More recent papers on At chemistry ==</div></td> </tr> </table> Lowercase sigmabot III