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Terbium(III) oxide

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Terbium(III) oxide
Names
Other names
terbium trioxide, terbia
Identifiers
ECHA InfoCard 100.031.668 Edit this at Wikidata
EC Number
  • 234-849-5
  • InChI=1/3O.2Tb/q3*-2;2*+3
Properties
O3Tb2
Molar mass 365.848 g·mol−1
Appearance white crystals
Melting point 2,410 °C (4,370 °F; 2,680 K)
Structure
Cubic, cI80
Ia-3, No. 206[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Terbium(III) oxide, also known as terbium sesquioxide, is a sesquioxide of the rare earth metal terbium, having chemical formula Tb
2
O
3
. It is a p-type semiconductor,[2] and may be prepared by the reduction of Tb
4
O
7
in hydrogen at 1300°C for 24 hours.[3]

References

  1. ^ Curzon A.E., Chlebek H.G. (1973). "The observation of face centred cubic Gd, Tb, Dy, Ho, Er and Tm in the form of thin films and their oxidation". J. Phys. F. 3: 1-5. doi:10.1088/0305-4608/3/1/009.
  2. ^ Reidar Haugsrud, Yngve Larring, and Truls Norby (2005). "Proton conductivity of Ca-doped Tb
    2
    O
    3
    ". Solid State Ionics. 176 (39–40). Elsevier B.V.: 2957–2961. doi:10.1016/j.ssi.2005.09.030.
    {{cite journal}}: Unknown parameter |month= ignored (help)CS1 maint: multiple names: authors list (link)
  3. ^ G. J. McCarthy (1971). "Crystal data on C-type terbium sesquioxide (Tb
    2
    O
    3
    )". Journal of Applied Crystallography. 4 (5): 399–400. doi:10.1107/S0021889871007295.
    {{cite journal}}: Unknown parameter |month= ignored (help)