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1-Naphthoic acid

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1-Naphthoic acid
Names
Other names
1-naphthylenecarboxylic acid
Identifiers
ECHA InfoCard 100.001.529 Edit this at Wikidata
Properties
C11H8O2
Molar mass 172.183 g·mol−1
Appearance white solid
Melting point 161 °C (322 °F; 434 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

1-Naphthoic acid is an organic compound of the formula C10H7CO2H. It is one of two isomeric carboxylic acid derivatives of naphthalene, the other one being 2-naphthoic acid. 1-Naphthoic acid is a frequent substrate for C-H activation reactions.[1] In general the hydroxynaphthoic acids are far more useful than the parent. It can be prepared by carboxylation of the Grignard reagent generated from 1-Bromonaphthalene.[2]

References

  1. ^ Mochida, Satoshi; Hirano, Koji; Satoh, Tetsuya; Miura, Masahiro (2011). "Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group". The Journal of Organic Chemistry. 76 (9): 3024–3033. doi:10.1021/jo200509m. PMID 21438629.
  2. ^ "α-Naphthoic Acid". Organic Syntheses. 11: 80. 1931. doi:10.15227/orgsyn.011.0080.