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Polymer-bonded explosive

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A polymer-bonded explosive, also called PBX or plastic-bonded explosive, is an explosive material in which explosive powder is bound together in a matrix using small quantities (typically 5-10% by weight) of a synthetic polymer ("plastic")

PBXes are normally used for explosive materials which are not easily meltable to cast or which are otherwise hard to form.

Polymer-bonded explosives have several potential advantages:

  • If the polymer matrix is an elastomer (rubbery material), it tends to absorb shocks, making the PBX very insensitive to accidental detonation.
  • Hard polymers can produce PBX that is very rigid, and maintains a precise engineering shape even under severe stress.
  • PBX powders can be pressed into a particular shape at room temperature, when casting normally requires hazardous melting of the explosive. High pressure pressing can achieve density for the material very close to the theoretical crystal density of the base explosive material.
  • Many PBXes are safe to machine to turn solid blocks into complex 3-dimentional shapes. This technique is used at nuclear weapons fabrication plants.
Some example PBXs
NameExplosive IngredientsBinder IngredientsUsage
X-024292% HMX8% polymer
EDC-3791% HMX/NC9% polyurethane rubber
PBXN-595% HMX5% fluoroelastomerNaval shells
PBXN-106RDXpolyurethane rubberNaval shells
LX-14-0 HMX 95.5%Estane & 5702-Fl 4.5%
LX-10-0 HMX 95%Viton-A 5%
LX-10-1 HMX 94.5%Viton-A 5.5%
PBX-9501HMX 95%Estane 2.5%; BDNPA-F 2.5%
PBX-9404HMX 94%NC 3%; CEF 3%
LX-09-1 HMX 93.3%BDNPA 4.4%; FEFO 2.3%
LX-09-0 HMX 93%BDNPA 4.6%; FEFO 2.4%
LX-07-2 HMX 90%Viton-A 10%
PBX-9011HMX 90%Estane and 5703-Fl 10%
LX-04-1 HMX 85%Viton-A 15%
LX-11-0 HMX 80%Viton-A 20%
LX-15 HNIS 95%Kel-F 800 5%
LX-16 PETN 96%FPC461 6%
PBX-9604RDX 96%Kel-F 800 4%
PBX-9407RDX 94%FPC461 6%
PBX-9205RDX 92%Polystyrene 6%; DOP 2%
PBX-9007RDX 90%Polystyrene 9.1%; DOP 0.5%; rosin 0.4%
PBX-9010RDX 90%Kel-F 3700 10%
PBX-9502TATB 95%Kel-F 800 5%
LX-17-0 TATB 92.5%Kel-F 800 7.5%
PBX-9503TATB 80%; HMX 15%Kel-F 800 5%

References:

Cooper, Paul W., Explosives Engineering, New York: Wiley-VCH, 1996. ISBN 0-471-18636-8