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Potassium chromate

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Potassium chromate
Names
IUPAC name
Potassium chromate
Other names
Chromic acid, (K2CrO4), dipotassium salt
Identifiers
3D model (JSmol)
ECHA InfoCard 100.029.218 Edit this at Wikidata
EC Number
  • 232-140-5
RTECS number
  • GB2940000
  • InChI=1S/Cr.2K.4O/q;2*+1;;;2*-1
  • [O-][Cr](=O)(=O)[O-].[K+].[K+]
Properties
CrK2O4
Molar mass 194.189 g·mol−1
Appearance Yellow odorless powder
Odor odorless
Density 2.7320 g/cm3
Melting point 968 °C (1,774 °F; 1,241 K)
Boiling point 1,000 °C (1,830 °F; 1,270 K)
62.9 g/100 mL (20 °C)
79.2 g/100 mL (100 °C)
Solubility insoluble in alcohol
1.74
Hazards
NFPA 704 (fire diamond)
Related compounds
Other anions
Potassium dichromate
Potassium molybdate
Potassium tungstate
Other cations
Sodium chromate
Calcium chromate
Barium chromate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium chromate (K2CrO4) is a yellow chemical indicator used for identifying concentrations of chloride ions in a salt solution with silver nitrate (AgNO3). It is a class two carcinogen and can cause cancer on inhalation.[1]

General information

Physical properties

Potassium Chromate is a lemon yellow compound that is in the form of a crystalline solid, and it is very stable.[citation needed]

Production

It is prepared by roasting powdered chromite with potash and limestone, treating the cinder with a hot potassium sulfate solution and leaching.

Alternatively, it may be prepared by the reaction of potassium dichromate and potassium hydroxide.

Reactions

When reacted with lead(II) nitrate, it creates an orange-yellow precipitate, lead(II) chromate. All ions hydrolyze in solution[citation needed].

Occurrence

Tarapacaite is the natural, mineral form of potassium chromate. It occurs very rarely and until now is known from only few localities on Atacama desert.[citation needed]

Safety

Potassium chromate is very toxic and may be fatal if swallowed. It may also act as a carcinogen, and can create reproductive defects if inhaled or swallowed. It also is a strong oxidizing agent if in the presence of H+ to produce the dichromate ion. It may react rapidly, or violently. It is also possible that it may react explosively with other reducing agents and flammable objects.

References

  1. ^ Potassium chromate information URL last accessed 15 March 2007