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Manganite

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Manganite
General
CategoryOxide mineral
Formula
(repeating unit)
MnO(OH)
Strunz classification04.FD.15
Dana classification06.01.03.01
Crystal systemMonoclinic, 2/m - prismatic, pseudo-orthorhombic
Identification
ColorDark steel-gray to black, reddish brown in transmitted light, gray-white with brownish tint, with blood-red internal reflections in reflected light
Crystal habitSlender prismatic crystals, massive to fibrous
TwinningContact and penetration twins on {011}
Cleavage{010} perfect, {110} and {001} good
FractureUneven
TenacityBrittle
Mohs scale hardness4
LusterSub-metallic
StreakReddish brown to nearly black
DiaphaneityOpaque, transparent on thin edges
Specific gravity4.29 - 4.34
Optical propertiesBiaxial (+)
Refractive indexnα = 2.250(2) nβ = 2.250(2) nγ = 2.530(2)
Birefringenceδ = 0.280, Bireflectance: distinct in grays
PleochroismFaint
2V angleSmall
DispersionVery strong
References[1][2][3][4]

Manganite is a mineral. Its composition is manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic).[1] Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish-brown. The hardness is 4, and the specific gravity is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Twinned crystals are not infrequent.

The mineral contains 89.7% manganese sesquioxide; it dissolves in hydrochloric acid with evolution of chlorine.

Occurrence

Manganite occurs with other manganese oxides in deposits formed by circulating meteoric water in the weathering environment in clay deposits and laterites. It forms by low temperature hydrothermal action in veins in association with calcite, barite, and siderite. Often associated with pyrolusite, braunite, hausmannite and goethite.[1][4]

Manganite occurs in specimens exhibiting good crystal form at Ilfeld in the Harz Mountains of Germay, where the mineral occurs with calcite and barite in veins traversing porphyry. Crystals have also been found at Ilmenau in Thuringia, Neukirch near Sélestat in Alsace (newkirkite), Granam near Towie in Aberdeenshire, and in Upton Pyne near Exeter, UK and Negaunee, Michigan, United States. As an ore of manganese it is much less abundant than pyrolusite or psilomelane.

Although described with various other names as early as 1772, the name manganite was first applied in a publication by W. Haidinger in 1827.[5]

Crystal structure of Manganite

References

  1. ^ a b c http://rruff.geo.arizona.edu/doclib/hom/manganite.pdf Handbook of Mineralogy
  2. ^ http://www.mindat.org/min-2519.html Mindat
  3. ^ http://webmineral.com/data/Manganite.shtml Webmineral data
  4. ^ a b Klein, Cornelis and Cornelius S. Hurbut, Jr., Manual of Mineralogy, Wiley, 20th ed., 1985, p. 317 ISBN 0-471-80580-7
  5. ^ Palache, Charles, Harry Berman and Clifford Frondel, The System of Mineralogy V. 1, p. 646, Wiley, 7th ed., 1944
  • Public Domain This article incorporates text from a publication now in the public domainChisholm, Hugh, ed. (1911). Encyclopædia Britannica (11th ed.). Cambridge University Press. {{cite encyclopedia}}: Missing or empty |title= (help)