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Description
English: TEM micrograph using osmium tetroxide to preferentially stain the polybutadiene matrix.

From the thermoplastic elastomers article:

"Block copolymers are interesting because they can "microphase separate" to form periodic nanostructures, as in the styrene-butadiene-styrene block copolymer shown at right. The polymer is known as Kraton and is used for shoe soles and adhesives. Owing to the microfine structure, the transmission electron microscope or TEM was needed to examine the structure. The butadiene matrix was stained with osmium tetroxide to provide contrast in the image. The material was made by living polymerization so that the blocks are almost monodisperse, so helping to create a very regular microstructure. The molecular weight of the polystyrene blocks in the main picture is 102,000; the inset picture has a molecular weight of 91,000, producing slightly smaller domains. The spacing between domains has been confirmed by small-angle X-ray scattering, a technique which gives information about microstructure. Since most polymers are incompatible with one another, forming a block polymer will usually result in phase separation, and the principle has been widely exploited since the introduction of the SBS block polymers, especially where one of the block is highly crystalline. One exception to the rule of incompatibility is the material Noryl, where polystyrene and polyphenylene oxide or PPO form a continuous blend with one another."

Date
Source Own work by the original uploader
Author Peter R Lewis
Other versions Also published in Polymer, 13, 22 (1972).

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Public domain This work has been released into the public domain by its author, Peterlewis at English Wikipedia. This applies worldwide.
In some countries this may not be legally possible; if so:
Peterlewis grants anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law.

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The original description page was here. All following user names refer to en.wikipedia.
  • 2008-02-29 09:17 Peterlewis 1018×717× (263502 bytes) TEM micrograph taken by author in 1970

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