Plutonium-242

Plutonium-242, ²⁴²Pu
General
Symbol	242Pu
Names	plutonium-242, 242Pu, Pu-242
Protons (Z)	94
Neutrons (N)	148
Nuclide data
Half-life (t1/2)	375000 years
Isotope mass	242.059 Da
Decay products	238U
Decay modes
Decay mode	Decay energy (MeV)
	Isotopes of plutonium ; Complete table of nuclides

Plutonium-242 (²⁴²Pu or Pu-242) is the second longest-lived isotope of plutonium, with a half-life of 375,000 years. The half-life of ²⁴²Pu is about 15 times that of ²³⁹Pu; so it is one-fifteenth as radioactive, and not one of the larger contributors to nuclear waste radioactivity. ²⁴²Pu's gamma ray emissions are also weaker than those of the other isotopes.^[1]

It is not fissile (but it is fissionable by fast neutrons), and its neutron capture cross section is low.

In the nuclear fuel cycle

Plutonium-242 is produced by successive neutron capture on ²³⁹Pu, ²⁴⁰Pu, and ²⁴¹Pu. The odd-mass isotopes ²³⁹Pu and ²⁴¹Pu have about a 3/4 chance of undergoing fission on capture of a thermal neutron and about a 1/4 chance of retaining the neutron and becoming the following isotope. The proportion of ²⁴²Pu is low at low burnup but increases nonlinearly.

²⁴²Pu has a particularly low cross section for thermal neutron capture; and it takes three neutron absorptions to become another fissile isotope (either curium-245 or plutonium-241) and then one more neutron to undergo fission. Even then, there is a chance either of those two fissile isotopes will absorb the fourth neutron instead of fissioning, becoming curium-246 (on the way to even heavier actinides like californium, which is a neutron emitter by spontaneous fission and difficult to handle) or becoming ²⁴²Pu again, so the mean number of neutrons absorbed until fission is even higher than 4. Therefore, ²⁴²Pu is particularly unsuited to recycling in a thermal reactor and would be better used in a fast reactor where it can be fissioned directly. However, ²⁴²Pu's low cross section means that relatively little of it is transmuted during one cycle in a thermal reactor.

Decay

Actinides and fission products by half-life v t e
Actinides^[2] by decay chain				Half-life range (a)	Fission products of ²³⁵U by yield^[3]
4n	4n + 1	4n + 2	4n + 3	Half-life range (a)	4.5–7%	0.04–1.25%	<0.001%
²²⁸Ra^№				4–6 a		¹⁵⁵Eu^þ
²⁴⁸Bk^[4]				> 9 a
²⁴⁴Cm^ƒ	²⁴¹Pu^ƒ	²⁵⁰Cf	²²⁷Ac^№	10–29 a	⁹⁰Sr	⁸⁵Kr	^113mCd^þ
²³²U^ƒ		²³⁸Pu^ƒ	²⁴³Cm^ƒ	29–97 a	¹³⁷Cs	¹⁵¹Sm^þ	^121mSn
	²⁴⁹Cf^ƒ	^242mAm^ƒ		141–351 a	No fission products have a half-life in the range of 100 a–210 ka ...
	²⁴¹Am^ƒ		²⁵¹Cf^ƒ^[5]	430–900 a
		²²⁶Ra^№	²⁴⁷Bk	1.3–1.6 ka
²⁴⁰Pu	²²⁹Th	²⁴⁶Cm^ƒ	²⁴³Am^ƒ	4.7–7.4 ka
	²⁴⁵Cm^ƒ	²⁵⁰Cm		8.3–8.5 ka
			²³⁹Pu^ƒ	24.1 ka
		²³⁰Th^№	²³¹Pa^№	32–76 ka
²³⁶Np^ƒ	²³³U^ƒ	²³⁴U^№		150–250 ka	⁹⁹Tc^₡	¹²⁶Sn
²⁴⁸Cm		²⁴²Pu		327–375 ka		⁷⁹Se^₡
				1.33 Ma	¹³⁵Cs^₡
	²³⁷Np^ƒ			1.61–6.5 Ma	⁹³Zr	¹⁰⁷Pd
²³⁶U			²⁴⁷Cm^ƒ	15–24 Ma		¹²⁹I^₡
²⁴⁴Pu				80 Ma	... nor beyond 15.7 Ma^[6]
²³²Th^№		²³⁸U^№	²³⁵U^ƒ№	0.7–14.1 Ga	... nor beyond 15.7 Ma^[6]
₡, has thermal neutron capture cross section in the range of 8–50 barns ƒ, fissile №, primarily a naturally occurring radioactive material (NORM) þ, neutron poison (thermal neutron capture cross section greater than 3k barns)

²⁴²Pu alpha decays into uranium-238, before continuing along the uranium series. ²⁴²Pu decays by spontaneous fission in about 5.5 × 10⁻⁴% of cases.^[7]

References

^ "PLUTONIUM ISOTOPIC RESULTS OF KNOWN SAMPLES USING THE SNAP GAMMA SPECTROSCOPY ANALYSIS CODE AND THE ROBWIN SPECTRUM FITTING ROUTINE" (PDF). Archived from the original (PDF) on 2017-08-13. Retrieved 2013-03-15.
^ Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
^ Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor.
^ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. Bibcode:1965NucPh..71..299M. doi:10.1016/0029-5582(65)90719-4.
"The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk²⁴⁸ with a half-life greater than 9 [years]. No growth of Cf²⁴⁸ was detected, and a lower limit for the β⁻ half-life can be set at about 10⁴ [years]. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 [years]."
^ This is the heaviest nuclide with a half-life of at least four years before the "sea of instability".
^ Excluding those "classically stable" nuclides with half-lives significantly in excess of ²³²Th; e.g., while ^113mCd has a half-life of only fourteen years, that of ¹¹³Cd is eight quadrillion years.
^ Chart of all nuclei which includes half life and mode of decay

[1] "PLUTONIUM ISOTOPIC RESULTS OF KNOWN SAMPLES USING THE SNAP GAMMA SPECTROSCOPY ANALYSIS CODE AND THE ROBWIN SPECTRUM FITTING ROUTINE" (PDF). Archived from the original (PDF) on 2017-08-13. Retrieved 2013-03-15.

[2] Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.

[3] Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor.

[4] Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. Bibcode:1965NucPh..71..299M. doi:10.1016/0029-5582(65)90719-4.
"The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk²⁴⁸ with a half-life greater than 9 [years]. No growth of Cf²⁴⁸ was detected, and a lower limit for the β⁻ half-life can be set at about 10⁴ [years]. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 [years]."

[5] This is the heaviest nuclide with a half-life of at least four years before the "sea of instability".

[6] Excluding those "classically stable" nuclides with half-lives significantly in excess of ²³²Th; e.g., while ^113mCd has a half-life of only fourteen years, that of ¹¹³Cd is eight quadrillion years.

[7] Chart of all nuclei which includes half life and mode of decay

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